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Pertanyaan

250 mL larutan penyangga terdiri dari larutan 0,2 M HCOOH dan larutan HCOOK 0,2 M. Kemudian ditambahkan lagi 50 mL larutan HCl 0,1 M. Berapakah pH campuran sebelum dan sesudah ditambah ? ( K a ​ HCOOH = 1 0 − 5 )

250 mL larutan penyangga terdiri dari larutan 0,2 M HCOOH dan larutan HCOOK 0,2 M. Kemudian ditambahkan lagi 50 mL larutan HCl 0,1 M. Berapakah pH campuran sebelum dan sesudah ditambah ?space

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M. Rani

Master Teacher

Mahasiswa/Alumni Universitas Brawijaya

Jawaban terverifikasi

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Pembahasan

Mol HCOOH = M V = 0,2 250 = 50 mmol, mol HCOOK = M V = 0,2 250 = 50 mmol, mol HCl = M V = 0,1 50 = 5 mmol. pH larutan sebelum ditambah HCl: Sedangkan pH setelah ditambah HCl adalah:

Mol HCOOH = Mcross timesV = 0,2cross times250 = 50 mmol, mol HCOOK = Mcross timesV = 0,2cross times250 = 50 mmol, mol HCl = Mcross timesV = 0,1cross times50 = 5 mmol.

pH larutan sebelum ditambah HCl:
 

table attributes columnalign right center left columnspacing 0px end attributes row cell open square brackets H to the power of plus sign close square brackets end cell equals cell K subscript a cross times fraction numerator n subscript as over denominator n subscript g middle dot val end fraction end cell row blank equals cell 10 to the power of negative sign 5 end exponent cross times fraction numerator 50 space mmol over denominator 50 space mmol middle dot 1 end fraction end cell row blank equals cell 10 to the power of negative sign 5 end exponent end cell row pH equals cell negative sign log space open square brackets H to the power of plus sign close square brackets end cell row blank equals cell negative sign log space 10 to the power of negative sign 5 end exponent end cell row blank equals 5 end table
 

Sedangkan pH setelah ditambah HCl adalah:
 

table attributes columnalign right center left columnspacing 0px end attributes row cell open square brackets H to the power of plus sign close square brackets end cell equals cell K subscript a cross times fraction numerator n subscript as and n subscript HCl over denominator n subscript g middle dot val bond n subscript HCl end fraction end cell row blank equals cell 10 to the power of negative sign 5 end exponent cross times fraction numerator left parenthesis 50 space plus 1 right parenthesis mmol over denominator left parenthesis 50 middle dot 1 minus sign 1 right parenthesis space mol end fraction end cell row blank equals cell 10 to the power of negative sign 5 end exponent cross times 51 over 49 end cell row blank equals cell 1 comma 04 cross times 10 to the power of negative sign 5 end exponent end cell row pH equals cell negative sign log space open square brackets H to the power of plus sign close square brackets end cell row blank equals cell negative sign log space 1 comma 04 cross times 10 to the power of negative sign 5 end exponent end cell row blank equals cell 5 minus sign log space 1 comma 04 end cell end table

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