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Asam fosfat dengan konsentrasi 0,9 M memiliki pH = 4. Jika K a 1 ​ = 7 , 59 × 1 0 − 8 , K a 2 ​ = 6 , 11 × 1 0 − 13 . Hitung konsentrasi dari ion fosfat yang terdapat dalam larutan.

Asam fosfat dengan konsentrasi 0,9 M memiliki pH = 4. Jika . Hitung konsentrasi dari ion fosfat yang terdapat dalam larutan.

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Y. Rochmawatie

Master Teacher

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dalam larutan tersebut adalah

 begin mathsize 14px style begin bold style left square bracket P O subscript 4 to the power of 3 minus sign end exponent right square bracket end style end style dalam larutan tersebut adalah begin mathsize 14px style bold 4 bold comma bold 6 bold middle dot bold 10 to the power of bold minus sign bold 14 end exponent bold space italic M bold. end style

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Beberapa asam lemah termasuk kedalam asam poliprotik, yaitu asam yang memiliki banyak proton. Disosiasi asam poliprotik terjadi dalam beberapa tahap, untuk asam fosfat, karena memiliki 3 proton maka disosiasinya mengalami 3 tahap dengan K pada masing-masing reaksi disosiasi. Menentukan nilai K pada larutan 0,9 M dan pH 9 Reaksi disosiasi Menentukan Jadi, dalam larutan tersebut adalah

Beberapa asam lemah termasuk kedalam asam poliprotik, yaitu asam yang memiliki banyak proton. Disosiasi asam poliprotik terjadi dalam beberapa tahap, untuk asam fosfat, karena memiliki 3 proton maka disosiasinya mengalami 3 tahap dengan K pada masing-masing reaksi disosiasi.

  • Menentukan nilai K pada larutan begin mathsize 14px style H subscript 3 P O subscript 4 end style 0,9 M dan pH 9

begin mathsize 14px style table attributes columnalign right center left columnspacing 0px end attributes row pH equals 4 row cell open square brackets H to the power of plus sign close square brackets end cell equals cell 10 to the power of negative sign 4 end exponent end cell row cell open square brackets H to the power of plus sign close square brackets end cell equals cell square root of K subscript a cross times M subscript a end root end cell row cell 10 to the power of negative sign 4 end exponent end cell equals cell square root of K cross times 9 cross times 10 to the power of negative sign 1 end exponent end root end cell row cell left parenthesis 10 to the power of negative sign 4 end exponent right parenthesis squared end cell equals cell left parenthesis square root of K subscript a cross times 9 cross times 10 to the power of negative sign 1 end exponent end root right parenthesis squared end cell row cell 10 to the power of negative sign 8 end exponent end cell equals cell K subscript a cross times 9 cross times 10 to the power of negative sign 1 end exponent end cell row cell K subscript a end cell equals cell fraction numerator 10 to the power of negative sign 8 end exponent over denominator 9 cross times 10 to the power of negative sign 1 end exponent end fraction end cell row blank equals cell 0 comma 11 cross times 10 to the power of negative sign 7 end exponent end cell row blank equals cell 1 comma 1 cross times 10 to the power of negative sign 6 end exponent end cell end table end style 

 

  • Reaksi disosiasi undefined

begin mathsize 14px style H subscript 3 P O subscript 4 equilibrium H to the power of plus sign and up diagonal strike H subscript 2 P O subscript 4 to the power of minus sign end strike space K subscript a equals 1 comma 1 cross times 10 to the power of negative sign 6 end exponent up diagonal strike H subscript 2 P O subscript 4 to the power of minus sign end strike equilibrium H to the power of plus sign plus up diagonal strike H P O subscript 4 to the power of 2 minus sign end exponent end strike space K subscript a 1 end subscript equals 7 comma 59 cross times 10 to the power of negative sign 8 end exponent fraction numerator up diagonal strike H P O subscript 4 to the power of 2 minus sign end exponent end strike equilibrium H to the power of plus sign plus P O subscript 4 to the power of 3 minus sign end exponent space K subscript a 2 end subscript equals 6 comma 11 cross times 10 to the power of negative sign 13 end exponent over denominator H subscript 3 P O subscript 4 equilibrium 3 H to the power of plus sign and P O subscript 4 to the power of 3 minus sign end exponent space K subscript a 3 end subscript equals 5 comma 10 cross times 10 to the power of negative sign 26 end exponent end fraction end style

 

  • Menentukan begin mathsize 14px style open square brackets P O subscript 4 to the power of 3 minus sign end exponent close square brackets end style

begin mathsize 14px style table attributes columnalign right center left columnspacing 0px end attributes row cell K subscript a 3 end subscript end cell equals cell fraction numerator open square brackets H to the power of plus sign close square brackets cubed left square bracket P O subscript 4 to the power of 3 minus sign end exponent right square bracket over denominator open square brackets H subscript 3 P O subscript 4 close square brackets end fraction end cell row cell left square bracket P O subscript 4 to the power of 3 minus sign end exponent right square bracket end cell equals cell fraction numerator K subscript a 3 end subscript cross times open square brackets H subscript 3 P O subscript 4 close square brackets over denominator open square brackets H to the power of plus sign close square brackets cubed end fraction end cell row blank equals cell fraction numerator 5 comma 1 cross times 10 to the power of negative sign 26 end exponent cross times 9 cross times 10 to the power of negative sign 1 end exponent over denominator open parentheses 10 to the power of negative sign 4 end exponent close parentheses cubed end fraction end cell row blank equals cell fraction numerator 45 comma 9 cross times 10 to the power of negative sign 27 end exponent over denominator 10 to the power of negative sign 12 end exponent end fraction end cell row blank equals cell 45 comma 9 cross times 10 to the power of negative sign 15 end exponent end cell row blank equals cell 4 comma 6 cross times 10 to the power of negative sign 14 end exponent end cell end table end style 

 

Jadi, begin mathsize 14px style begin bold style left square bracket P O subscript 4 to the power of 3 minus sign end exponent right square bracket end style end style dalam larutan tersebut adalah begin mathsize 14px style bold 4 bold comma bold 6 bold middle dot bold 10 to the power of bold minus sign bold 14 end exponent bold space italic M bold. end style

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